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Regulation 7(1) and (2) and paragraph 2(c)of Part 1 of Schedule 3, paragraph 2(c) of Part 2 of Schedule 3 and Notes 1 and 2 of Schedule 7

SCHEDULE 6 Maximum limits for constituents of natural mineral waters

  

Constituents Maximum limits (mg/l)
Antimony 0.0050
Arsenic 0.010 (as total)
Barium 1.0
Cadmium 0.003
Chromium 0.050
Copper 1.0
Cyanide 0.070
Fluoride 5.0
Lead 0.010
Manganese 0.50
Mercury 0.0010
Nickel 0.020
Nitrate 50
Nitrite 0.1
Selenium 0.010

Note:

The constituents described above refer to constituents naturally present in the water at source and not to substances present as the result of contamination.

Regulation 7(2)

SCHEDULE 7 Performance characteristics for analysing the constituents in Schedule 6

  

Constituent Accuracy of parametric value in % Precision of parametric value Detection limit of parametric value in %
Antimony 25 25 25
Arsenic 10 10 10
Barium 25 25 25
Cadmium 10 10 10
Chromium 10 10 10
Copper 10 10 10
Cyanides 10 10 10
Fluoride 10 10 10
Lead 10 10 10
Manganese 10 10 10
Mercury 20 10 20
Nickel 10 10 10
Nitrate 10 10 10
Nitrite 10 10 10
Selenium 10 10 10

Notes:

1.  The method of analysis used to measure the concentration of the constituents in Schedule 6 must be capable of measuring concentrations equal to the parametric value with the specified accuracy, precision and detection limits.

2.  Regardless of the sensitivity of the method of analysis, the result must be expressed to at least the same number of decimal places as the maximum limit set out in Schedule 6 for the particular constituent being analysed.

3.  Accuracy is the systematic error and represents the difference between the average value of a large number of repeated measurements and the exact value.

4.  Precision represents the random error and is expressed in general as the standard deviation (within a batch and between batches) of a sample of results from the average.

5.  Acceptable precision is equal to twice the relative standard deviation.

6.  The detection limit is—

(a) three times the relative standard deviation within a batch of a natural sample containing a low concentration of the constituent; or

(b) five times the relative standard deviation within a batch of a virgin sample.

7.  The method should make it possible to determine cyanide in all its forms.